Organometallic chemistry of metal surfaces - ultra high vacuum studies

Organometallic chemistry on silicon and germanium surfaces.

Multifunctional ultra-high vacuum apparatus for studies of the interactions of chemical warfare agents on complex surfaces A fundamental understanding of the surface chemistry of chemical warfare agents

Multifunctional ultra-high vacuum apparatus for studies of the interactions of chemical warfare agents on complex surfaces Report Title A fundamental understanding of the surface chemistry of chemical warfare agents is needed to fully predict the interaction of these toxic molecules with militarily relevant materials, catalysts, and environmental surfaces. For example, rules for predicting the ...

Organometallic chemistry

This Thematic Series is dedicated to the memory of Professor Peter Hofmann (Figure 1) whose research work included many seminal contributions to the field of organometallic chemistry [1-3]. Organometallic chemistry has therefore been chosen as the topic of this Thematic Series of the Beilstein Journal of Organic Chemistry. Over a period of many decades, the chemistry of metal–carbon bonds has g...

Molecular metal catalysts on supports: organometallic chemistry meets surface science.

Recent advances in the synthesis and characterization of small, essentially molecular metal complexes and metal clusters on support surfaces have brought new insights to catalysis and point the way to systematic catalyst design. We summarize recent work unraveling effects of key design variables of site-isolated catalysts: the metal, metal nuclearity, support, and other ligands on the metals, a...

Medicinal organometallic chemistry: designing metal arene complexes as anticancer agents.

The field of medicinal inorganic chemistry is rapidly advancing. In particular organometallic complexes have much potential as therapeutic and diagnostic agents. The carbon-bound and other ligands allow the thermodynamic and kinetic reactivity of the metal ion to be controlled and also provide a scaffold for functionalization. The establishment of structure-activity relationships and elucidatio...